| 新型双联阴离子表面活性剂的合成与表面活性研究 |
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| 引用本文： | 赵田红,胡星琪,王忠信,彭国峰,谷秋志. 新型双联阴离子表面活性剂的合成与表面活性研究[J]. 精细石油化工, 2007, 24(3): 7-11 |
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| 作者姓名： | 赵田红 胡星琪 王忠信 彭国峰 谷秋志 |
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| 作者单位： | 西南石油大学化学化工学院,四川,成都,610500;西南石油大学化学化工学院,四川,成都,610500;油气藏地质及开发工程国家重点实验室,四川,成都,610500;大庆油田有限责任公司第一采油厂,黑龙江,大庆,163000;大庆石化公司塑料厂,黑龙江,大庆,163000 |
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| 基金项目： | 四川省重点学科建设项目(SZD0413)． |
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| 摘 要： | 以乙二胺、月桂酰氯、2-溴乙基磺酸钠为原料制备了阴离子型Gemini表面活性剂乙撑-双(N-乙磺酸-十二酰胺)钠盐(简称DTM-12)。以IR和~1H NMR对其结构进行了初步表征,考察了无机盐和醇对DTM-12表面活性的影响。结果表明;DTM-12水溶液的cmc为5.0×10~(-4)mol/L),γ_(cmc)为29.7 mN/m;DTM-12与DTAB组成的复配体系在摩尔比为3:7时,cmc可达1.06×10~(-4)mol/L,γ_(cmc)可达25.4 mN/m,优于十二烷基磺酸钠组成的复配体系。
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| 关 键 词： | 双子表面活性剂 合成 表面活性 复配性质 |
| 收稿时间： | 2006-11-16 |
| 修稿时间： | 2006-11-162007-04-20 |
STUDY ON SYNTHESIS AND SURFACE ACTIVITY OF AN ANIONIC GEMINI SURFACTANT |
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| Zhao Tianhong,Hu Xingqi,Wang Zhongxin,Peng Guofeng,Gu Qiuzhi. STUDY ON SYNTHESIS AND SURFACE ACTIVITY OF AN ANIONIC GEMINI SURFACTANT[J]. Speciality Petrochemicals, 2007, 24(3): 7-11 |
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| Authors: | Zhao Tianhong Hu Xingqi Wang Zhongxin Peng Guofeng Gu Qiuzhi |
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| Abstract: | Gemini type ethylene-(N,N′-bis-sodium ethylene sulfonate dodecylamide)(DTM-12)was synthesized from ethylenediamine,lauroyl chloride and 2-Bromoethylene-sulfonate.The structure of the product was characterized with IR and ~1H NMR spectra.The cmc value(5.0×10~(-4)mol/L)of the aqueous solution of DTM-12 was one-sixteenth and one-twentieth as smaller as sodium dodecyl-sul- phate and sodium dodecyl-sulfonate,respectively,and theγ_(cmc)(29.7 mN/m)was also 8-9 mN/m lower than the latter two surfactants.The effects of salt and alcohol on the surface tension of the syn- thesized surfactant were measured.The composite of DTM-12+DTAB with 3:7 moles had better surface activity than sodium dodecyl-sulfonate composite system with cmc value of 1.06×10~(-4)mol/L andγ_(cmc)value of 25.4 mN/m. |
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| Keywords: | Gemini surfactant synthesis surface activity composite property |
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