| α,β不饱和酮和酰胺的二茂铁衍生物的质谱研究 |
| |
| 引用本文： | 傅桂香 俞璐. α,β不饱和酮和酰胺的二茂铁衍生物的质谱研究[J]. 质谱学报, 1994, 15(2): 68-76 |
| |
| 作者姓名： | 傅桂香 俞璐 |
| |
| 作者单位： | 中国科学院上海有机化学研究所，华东理工大学化学系 |
| |
| 摘 要： | 本文报道α、β不饱和酮和酰胺的二茂铁衍生物的电子轰击质谱（ＥＩＭＳ），并利用高分辨质谱（ＨＲＭＳ）数据和ＭＳ／ＭＳ联用技术研究了该类化合物的裂解规律，还研究了直接进样探头温度对谱图的影响。
|
| 关 键 词： | 二茂铁衍生物，HRMS，MS／MS |
Mass Spectra of Ferrocenylethylene Formacyl Derivatives |
| |
| Fu Guixiang,Yu Lu, Huang Jiling. Mass Spectra of Ferrocenylethylene Formacyl Derivatives[J]. Journal of Chinese Mass Spectrometry Society, 1994, 15(2): 68-76 |
| |
| Authors: | Fu Guixiang Yu Lu Huang Jiling |
| |
| Abstract: | The mass spectra of the title compounds have been reported. The fragmentation patterns and the structure of fragment ion have been examined by means of the MS/MS technique and high resolution mass spectrometer. The major ions presented in all spectra are moleculars ion and [M-C5H5] ion. The rearrangement reaction of the R group has been observed. The spectral patterns of the title compounds are temperature sensitive. Some of the ions ill the spectra and hydrogenation seem to be formed in more high temperature of t.he sample heater. |
| |
| Keywords: | ferrocenylelthylene formacyl HRMS MS/MS. |
| 本文献已被 CNKI 维普 等数据库收录！ |
