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Gaseous detonation fabrication of CNTs and CNTs doping with Fe based composites
Authors:Ning Luo  Hongwen Jing
Affiliation:1. State Key Laboratory for Geo-mechanics and Deep Underground Engineering, School of Mechanics and Civil Engineering, China University of Mining and Technology, Xuzhou, China;2. Laboratory for Precision and Nano Processing Technologies, School of Mechanical and Manufacturing Engineering, The University of New South Wales, Sydney2052, Australia
Abstract:The carbon nanotubes (CNTs) and CNTs doping with Fe based composites were rapid fabricated by gaseous detonation decomposition of oxygen, benzene and ferrocene mixed precursors. A series of novel experiments were designed to investigate the condensation and formation of carbon structural nanomaterials. The TEM, EDS, EDX, XRD and Raman characterizations provide fundamental evidence of the high yield and purity of the CNTs, CNTs doping with Fe composites during the gaseous detonation reaction process. The results showed that CNTs, CNTs with Fe based nanocrystals, spherical CCFNPs and their mixed products are with variant morphologies. The obtained CNTs is multi-walled carbon nanotubes and CNTs doping with a body-centered cubic iron or iron carbide cores, which can be obtained respectively through adjusting and controlling the detonation reaction environment and the precursors.
Keywords:carbon nanotubes  detonation  Fe based composites  gaseous mixture
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