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The Effect of a Changing Lean Gas Composition on the Ability of NO2 Formation and NOx Reduction over Supported Pt Catalysts
Authors:Louise Olsson  Miroslawa Abul-Milh  Hanna Karlsson  Edward Jobson  Peter Thormählen and Andreas Hinz
Affiliation:(1) Competence Centre for Catalysis, Chalmers University of Technology, SE-412 96 Göteborg, Sweden;(2) Dept. 06130, Volvo Technology Corporation, SE-405 08 Göteborg, Sweden
Abstract:Three model catalysts (Pt/Al2O3, Pt/TiO2, Pt/V2O5/TiO2) were examined in regard to their NO2 formation ability under a changing lean gas composition. The results show that the NO to NO2 oxidation function as well as the NO x reduction under lean gas conditions is affected by a change in the lean gas atmosphere. The NO oxidation activity also decreased with time, for Pt/Al2O3 and Pt/TiO2, and a possible explanation may be platinum oxide formation. This deactivation was not observed for Pt/V2O5/TiO2.
Keywords:Pt/Al2O3  Pt/TiO2  Pt/V2O5/TiO2  oxidation  NO  NO x   NO2  lean burn conditions  platinum oxides
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