Hydrothermal synthesis and crystal structure of a neutral cyclic tetranuclear cobalt(II) complex with 5-nitrosalicylate and 1,10-phenanthroline ligands |
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| Authors: | De-Cai Wen Tian-Yang Xie |
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| Affiliation: | aDepartment of Chemistry, Longyan University, Longyan 364000, PR China |
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| Abstract: | A novel complex, Co4(phen)4{5-(NO2)sal}4 (1) (5-(NO2)sal = 5-nitrosalicylate anion, phen = 1,10-phenanthroline), have been prepared by hydrothermal synthesis and characterized by single crystal X-ray analysis, IR, TG, cyclic voltammogram and elemental analyses. This complex displays a neutral metallamacrocyclic structure containing [Co(phen)]2+ corner units and 5-(NO2)sal bridging ligands. |
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| Keywords: | Metallamacrocycle Hydrothermal synthesis 5-Nitrosalicylate Cobalt(II) |
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