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α-Fe_2O_3单分散溶胶在EDTA溶液中的稳定性
引用本文:张玉亭,吕彤.α-Fe_2O_3单分散溶胶在EDTA溶液中的稳定性[J].天津工业大学学报,1991(4).
作者姓名:张玉亭  吕彤
作者单位:天津纺织工学院纺化系,天津纺织工学院纺化系
基金项目:国家自然科学基金,项目编号:化学2860108
摘    要:EDTA的浓度和介质PH的变化可以引起a-Fe_2O_3单分散溶胶的絮凝和再稳定。再稳定是由于带有正电荷的胶体粒子吸附了过剩的负离子,导致粒子表面电性反号引起的。C.C.C和C.S.C强烈依赖于介质的PH。该絮凝机理属于吸附凝机理,受表面化学反应所控制。

关 键 词:反电离子  EDTA  絮凝  再稳定

Stability of Monodispersed Hematite Sols in the Presence of the EDTA Solution
Zhang Yuting,Lu Tong Dept.of Text.Chem.Eng..Stability of Monodispersed Hematite Sols in the Presence of the EDTA Solution[J].Journal of Tianjin Polytechnic University,1991(4).
Authors:Zhang Yuting  Lu Tong Deptof TextChemEng
Affiliation:Zhang Yuting;Lu Tong Dept.of Text.Chem.Eng.
Abstract:Coagulation and stabilization of monodispersed hematite sols may be caused by con- centration of the EDTA and change of the PH of the medium.The restabilization is caused by reversal of charge due to adsorption of the excess negatively ions on positively charged sols.Critital coagulation concentration(C.C.C)and critital stabilization concentration (C.S.C)intensely depend on the PH of the medium.Coagulation mechanism belongs in adsorption coagulation mechanism which is controlled by surface chemical reaction.
Keywords:counterions  EDTA  coagulation  restabilization  
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