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纤维掺杂疏水SiO2气凝胶的制备与表征
引用本文:张志华,沈军,倪星元,李洋,王博,吴广明,周斌.纤维掺杂疏水SiO2气凝胶的制备与表征[J].稀有金属材料与工程,2008,37(Z2):16-19.
作者姓名:张志华  沈军  倪星元  李洋  王博  吴广明  周斌
作者单位:同济大学,波耳固体物理研究所,上海,200092
基金项目:National Natural Science Foundation of China(No.20133040),Chinese National Foundation of High Technology (2002AA842052),Shanghai Committee of Science and Technology(055211010,0352nm056,0452nm088),Shanghai Key Subject Program,Shanghai Phosphor Program(05QMH1413)
摘    要:采用溶胶-凝胶方法成功制备了陶瓷纤维掺杂的疏水SiO2气凝胶.陶瓷纤维在SiO2气凝胶中起骨架支撑的作用来提高气凝胶的机械性能.SiO2气凝胶的机械强度从没有掺杂纤维的1.6×104Pa提高到掺杂10%纤维的9.6X 104Pa,且掺杂10%纤维的SiO2气凝胶常温常压的热导率仅为0.029 W/(m·K).掺杂SiO2气凝胶的疏水性通过表面修饰也得到了极大的提高.

关 键 词:纤维掺杂SiO2气凝胶  溶胶-凝胶  机械性能  热导率
文章编号:1002-185X(2008)S2-016-04
修稿时间:2007年11月12

Preparation and Characterization of Hydrophobic Silica Aerogels Doped with Fibers
Zhang Zhihua,Shen Jun,Ni Xingyuan,Li Yang,Wang Bo,Wu Guangming,Zhou Bin.Preparation and Characterization of Hydrophobic Silica Aerogels Doped with Fibers[J].Rare Metal Materials and Engineering,2008,37(Z2):16-19.
Authors:Zhang Zhihua  Shen Jun  Ni Xingyuan  Li Yang  Wang Bo  Wu Guangming  Zhou Bin
Abstract:Hydrophobic silica aerogel doped with ceramic fibers were prepared successfully via sol-gel process.The ceramic fibers were distributed inside the silica aerogels to act as a supporting skeleton material,which improved the mechanical property.The mechanical strength of the silica aerogels increases from 1.6×104 Pa to 9.6 ×104 Pa with the doping of 10%doped aerogels are increased a lot by surface modification.
Keywords:silica aerogels doped with fibers  sol-gel  mechanical property  thermal conductivity
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