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Electrical properties of new tin dioxide varistor ceramics at high currents
Authors:Zhen-Ya Lu  AB Glot  AI Ivon  Zi-Yang Zhou
Affiliation:1. South China University of Technology, Guangzhou 510640, China;2. Universidad Tecnológica de la Mixteca, Huajuapan de León, Oaxaca 69000, Mexico;3. Dniepropetrovsk National University, Dniepropetrovsk 49010, Ukraine;1. University of Tabriz, Faculty of Physics, Emam St., Tabriz, Iran;2. University of Tabriz, Faculty of Chemistry, Tabriz, Iran;1. Department of Materials Science and Engineering, Yonsei University, Seoul 120-749, Republic of Korea;2. CIJ Co. Ltd., Daejeon 305-343, Republic of Korea;1. Carretera a Salinas Victoria, km. 2.3, C.P. 66600 Apodaca, NL, México;2. Universidad Autónoma de Nuevo León, Facultad de Ingeniería Mecánica y Eléctrica, Centro de Investigación e Innovación en Ingeniería Aeronáutica (CIIIA), C.P. 66600 Apodaca, NL, México;3. Universidad Autónoma de Nuevo León, Facultad de Ingeniería Mecánica y Eléctrica, Av. Pedro de Alba s/n, Ciudad Universitaria, C.P. 66455 San Nicolás de los Garza, NL, Mexico;4. Universidad Tecnológica de La Mixteca, Huajuapan, 69000 Oaxaca, Mexico;5. Universidad Autónoma de Coahuila, Facultad de Metalurgia, Carr. 57, Km 4.5, C.P. 25710 Monclova, Coah., México
Abstract:New dense SnO2-based varistor ceramics with high nonlinear current–voltage characteristics (nonlinearity coefficients are of approximately 50) in a system of SnO2–CoO–Nb2O5–Cr2O3–Y2O3–SrO–MgO are reported. The current–voltage behaviour at high currents is studied by using exponential voltage pulses. The obtained SnO2 varistor ceramics exhibit low grain resistivity values of 0.23–0.64 ohm cm. To date, such values are the lowest known for SnO2 varistors, and are closely approaching the grain resistivity of the ZnO varistor. The current–voltage characteristics of the obtained SnO2-based varistor materials are reproducible in a wide current range from 10?11 to approximately 104 A cm?2. The minimum current density and the minimum electric field necessary to cause the irreversible electrical breakdown are measured. It is established that a decrease in the grain resistivity leads to an increase in the minimum current density necessary for irreversible electrical breakdown to occur.
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