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溴酸钾氧化甲基绿催化光度法测定痕量钯
引用本文:周之荣.溴酸钾氧化甲基绿催化光度法测定痕量钯[J].稀有金属,1998,22(5):355-357.
作者姓名:周之荣
作者单位:华东地质学院应用化学系,临川,344000
摘    要:研究了稀硫酸介质中痕量Pd(Ⅱ)催化溴酸钾氧化甲基绿的褪色反应及动力学条件,建立了高灵敏度测定痕量Pd(Ⅱ)的新催化光度法。方法的灵敏度为567×10-12g/ml,线性范围为0~01μg/25ml。用于测定矿石中的痕量钯,结果较好。

关 键 词:Pd(Ⅱ)  溴酸钾  甲基绿  催化动力学光度法

Catalytic Spectrophotometric Determination of Trace Palladium Based on Oxidation of Methyl Green with Potassium Bromate
Zhou Zhirong.Catalytic Spectrophotometric Determination of Trace Palladium Based on Oxidation of Methyl Green with Potassium Bromate[J].Chinese Journal of Rare Metals,1998,22(5):355-357.
Authors:Zhou Zhirong
Abstract:The necessity and possibility of replacement of noble metals by rare earth elements in the automobile exhaust catalyst control technology were elucidated. The type and the component of three way catalysts (TWC), the role of rare earth elements in TWC, the application prospect of rare earth containing TWC and their market potential were presented. It is indicated that development and the commercialization of rare earth containing three way catalysts are advantageous to find a way out of the harsh difficulty of atmospheric pollution in our country and to make a change from domestic RE conventional Industry to RE high tech. trade.
Keywords:Noble metal three way catalyst  Rare earth  containing three way catalyst  Automobile exhaust control  Environment engineering
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