| 空穴传输材料在高效钙钛矿太阳能电池中的发展演变 |
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| 引用本文： | 邹金龙,罗玉峰,肖宗湖,胡云,饶森林,刘绍欢.空穴传输材料在高效钙钛矿太阳能电池中的发展演变[J].材料导报,2018,32(15):2542-2554, 2570. |
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| 作者姓名： | 邹金龙 罗玉峰 肖宗湖 胡云 饶森林 刘绍欢 |
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| 作者单位： | 南昌大学机电工程学院,南昌,330031
南昌大学机电工程学院,南昌 330031;华东交通大学机电与车辆工程学院,南昌 330031
新余学院新能源科学与工程学院,新余 338004;新余新能源研究所,新余 338004
新余学院新能源科学与工程学院,新余,338004 |
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| 基金项目： | 国家自然科学基金(51462035)，江西省高等学校科技落地计划项目(KJLD13099)，江西省技术创新引导类科技计划专利产业化专项(20161BBM26039) |
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| 摘 要： | 钙钛矿太阳能电池(PSCs)转换效率已从2009年的3.8%上升到2017年的22.7%,其快速的发展可能使光伏工业进入革命新阶段。空穴传输材料(HTM)是构成高效钙钛矿太阳能电池的重要组成部分,开发和设计导电性好、成本低、稳定性好的空穴传输层材料对钙钛矿太阳能电池的研究显得非常重要。本文将近几年应用于钙钛矿太阳能电池中较高效的空穴传输材料归纳为有机小分子类、有机聚合物类和无机材料类,同时也介绍了无空穴传输层的钙钛矿电池。详细评述了基于各类空穴传输材料的钙钛矿太阳能电池的光电性能及稳定性,重点讨论了HOMO能级、空穴迁移率、添加剂的掺杂等因素对钙钛矿太阳能电池的影响。最后指出了空穴传输材料未来的研究重点和发展趋势。
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| 关 键 词： | 钙钛矿太阳能电池 空穴传输材料 光电转换效率(PCE) 无空穴传输层钙钛矿太阳能电池 |
The Evolvement of Hole-transporting Materials in Highly Efficient Perovskite Solar Cells |
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| ZOU Jinlong,LUO Yufeng,XIAO Zonghu,HU Yu,RAO Senlin and LIU Shaohuan.The Evolvement of Hole-transporting Materials in Highly Efficient Perovskite Solar Cells[J].Materials Review,2018,32(15):2542-2554, 2570. |
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| Authors: | ZOU Jinlong LUO Yufeng XIAO Zonghu HU Yu RAO Senlin and LIU Shaohuan |
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| Affiliation: | School of Mechanical and Electronic Engineering, Nanchang University, Nanchang 330031,School of Mechanical and Electronic Engineering, Nanchang University, Nanchang 330031;School of Mechatronics & Vehicle Engineering, East China Jiaotong University, Nanchang 330031,School of New Energy Science and Engineering, Xinyu College, Xinyu 338004;New Energy Research Institute of Xinyu, Xinyu 338004,School of New Energy Science and Engineering, Xinyu College, Xinyu 338004,School of New Energy Science and Engineering, Xinyu College, Xinyu 338004 and School of New Energy Science and Engineering, Xinyu College, Xinyu 338004 |
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| Abstract: | The perovskite solar cells (PSCs) have acquired a pronounced power conversion efficiency (PCE) improvement from 3.8% in 2009 to 22.7% in 2017, which may lead to a revolutionary new age for photovoltaic industry. Hole-transporting mate-rial (HTM) is a crucial part of highly efficient PSC, and the development and design of highly conductive, low-cost and highly-stable hole-transporting materials are of remarkable significance for the PSC R&D. This paper provides an elaborate delineation of the HTM that have emerged in recent years and applied to relatively high-efficiency PSCs, by classifying HTM into small molecule organic compounds, organic polymers and inorganic compounds, and also offers an introduction on the research evolution of hole-conductor-free PSCs, with emphases on the photovoltaic performances and stability of PSCs based on various HMT or without HMT. Finally, the future research trends are presented. |
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| Keywords: | perovskite solar cell hole-transporting material power conversion efficiency (PCE) hole-conductor-free perovskite solar cell |
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