| 聚苯胺Ni~(2 )膜修饰电极对甲醇的电催化氧化研究 |
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| 引用本文： | 李念兵,向斌,张胜涛,丁培道.聚苯胺Ni~(2 )膜修饰电极对甲醇的电催化氧化研究[J].精细化工,2000(Z1). |
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| 作者姓名： | 李念兵 向斌 张胜涛 丁培道 |
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| 作者单位： | 重庆大学环境与化学化工学院!重庆400044 |
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| 摘 要： | 将电聚合的聚苯胺 (PAN)膜电极置于c(NiSO4 ) =2 5mol/L的溶液中浸泡 2 0min得到嵌入Ni2 的PAN Ni2 电极 ,该电极在KOH溶液中的循环伏安曲线于 0 30 7V/0 2 30V处有一对明显的氧化还原电流峰 ,表明Ni2 离子已嵌入PAN膜电极。PAN Ni2 电极对碱性介质中甲醇的氧化具有明显的电催化活性。
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| 关 键 词： | PANNi2 膜电极 电催化 甲醇 |
Electrocatalytic Oxidation of Methanol on PAN Ni\ \{2 \} Film Modified Electrode |
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| LI Nian bing,XIANG Bin,ZHANG Sheng tao,DING Pei dao.Electrocatalytic Oxidation of Methanol on PAN Ni\ \{2 \} Film Modified Electrode[J].Fine Chemicals,2000(Z1). |
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| Authors: | LI Nian bing XIANG Bin ZHANG Sheng tao DING Pei dao |
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| Abstract: | PAN Ni 2 electrode was prepared using polyaniline film immersed in a solution of 2.5 mol/L NiSO\-4 for about 20 minutes.The voltammetric behavior of the PAN Ni 2 electrode in alkaline aqueous solution showed that a couple of redox current peaks appeared at potentials of 0.307 V and 0.230 V,which indicated that Ni 2 has been embedded into the PAN film.The PAN Ni 2 film acted as an active substance for the electrocatalytic oxidation of methanol in alkaline solutions. |
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| Keywords: | PAN Ni 2 film electrode electrocatalytic oxidation methax |
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