| 磷配体在氨甲酰化反应中的应用 |
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| 引用本文： | 蒋文 吴良泉. 磷配体在氨甲酰化反应中的应用[J]. 上海化工, 2006, 31(5): 30-34 |
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| 作者姓名： | 蒋文 吴良泉 |
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| 作者单位： | 上海焦化有限公司,上海200241 |
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| 摘 要： | 综述了烯烃氧甲酰化反应中所应用的膦和亚磷酸酯两大类配体，其研究经历了单磷、双磷及单磷配体再度兴起的过程。列举了一些有代表性的配体及理论。配体研究的发展过程始终围绕着既能提高催化活性又能提高目的产物区域选择性这个主题。
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| 关 键 词： | 氧甲酰化 配体 膦亚磷酸酯 烯烃 |
| 收稿时间： | 2006-04-01 |
| 修稿时间： | 2006-04-01 |
Progress in Phosphorous Ligands for Hydroformylation of Olefin |
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| Jiang Wen, Wu Liangquan. Progress in Phosphorous Ligands for Hydroformylation of Olefin[J]. Shanghai Chemical Industry, 2006, 31(5): 30-34 |
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| Authors: | Jiang Wen Wu Liangquan |
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| Abstract: | Phosphine ligands and phosphite ligands for hydroformylation of olefin were reviewed, and some representative ligands and theories were summarized.Stages of research progress in phosphorous ligands are monodentate ligands, didentare ligands and monodentate again. Studying ligands is concerned about promoting catalyst activity and regioselectivity. |
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| Keywords: | Hydroformylation Ligand Phosphine Phosphite Olefin |
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