| 自组装中孔BCN化合物的合成与表征 |
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| 引用本文： | 黄小建,张渊,戴启武,陈晓蓉.自组装中孔BCN化合物的合成与表征[J].陶瓷科学与艺术,2011(2). |
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| 作者姓名： | 黄小建 张渊 戴启武 陈晓蓉 |
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| 作者单位： | 南京工业大学化学化工学院; |
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| 基金项目： | 国家自然科学基金资助项目(20802008) |
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| 摘 要： | 以三聚氰胺和硼氢化钠为原料合成具有中孔结构的新颖硼碳氮(BCN)化合物,采用热质量-差示扫描量热(TG-DSC)、X线衍射(XRD)、氮吸附比表面积(BET)、傅立叶红外光谱(FT-IR)、扫描电镜(SEM)、透射电镜(TEM)和荧光光谱(PL)等分析手段对BCN化合物进行表征,研究BCN化合物光致发光性能。结果表明:热分解温度在600℃以上可制备出具有层状石墨结构的BCN化合物。随热分解温度升高至800℃,B、N含量增大,C含量减小,得到化学计量比为2∶1∶2的B2 CN2化合物。荧光光谱(PL)测试证明BCN化合物具有光致发光性。
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| 关 键 词： | BCN化合物 中孔 层状石墨结构 |
Synthesis and characterization of micropous BCN compound by self-assembly |
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| HUANG Xiaojian,ZHANG Yuan,DAI Qiwu,CHEN Xiaorong.Synthesis and characterization of micropous BCN compound by self-assembly[J].Ceramics Science & Art,2011(2). |
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| Authors: | HUANG Xiaojian ZHANG Yuan DAI Qiwu CHEN Xiaorong |
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| Affiliation: | HUANG Xiaojian,ZHANG Yuan,DAI Qiwu,CHEN Xiaorong(College of Chemistry & Chemical Engineering,Nanjing University of Technology,Nanjing 210009,China) |
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| Abstract: | A mesoporous boron-carbon-nitrogen(BCN) compound was synthesized by using C3H6N6 and NaBH4 as the raw materials,and characterized by thermo-gravimetric and differential scanning calorimetry(TG-DSC),X-ray diffraction(XRD),N2 adsorption for specific surface area(BET),Fourier transform infrared spectroscopy(FT-IR),scanning electron microscope(SEM),transmission electron microscope(TEM) and photoluminescence(PL) property.The results indicated that the BCN compound had the structure of graphitic layers when the t... |
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| Keywords: | BCN compounds mesoporous graphitic layer structure |
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