| 9,9-双（甲氧基甲基）芴的合成及其应用研究 |
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| 引用本文： | 熊斌,涂媛鸿,廖维林,许招会.9,9-双（甲氧基甲基）芴的合成及其应用研究[J].江西化工,2008(4):117-120. |
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| 作者姓名： | 熊斌 涂媛鸿 廖维林 许招会 |
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| 作者单位： | 江西省精细化工重点实验室,江西,南昌,330027 |
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| 基金项目： | 国家自然科学基金项目资助
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国家科技攻关计划项目资助
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| 摘 要： | 9,9-双（甲氧基甲基）芴（BMMF）的合成分两步进行：首先,在乙醇钠催化剂的作用下,芴与多聚甲醛反应合成了中间体9,9-双（羟甲基）芴（BHMF）,然后以四丁基溴化铵（TBAB）为相转移催化剂,再与氯甲烷发生烷基化反应合成了9,9-双甲氧基甲基芴。用9,9-双（羟甲基）芴作外给电子体进行了丙烯聚合应用,实验结果表明：9,9-双（甲氧甲基）芴（BMMF）是聚丙烯Ziegler-Natta催化体系较好的外给电子体。
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| 关 键 词： | 9 9-双(甲氧基甲基)芴 9 9-双(羟甲基)芴 给电子体 相转移催化 |
Synthesis of 9,9-bis(methoxymethyl)fluorene and its application |
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| Xiong Bin,Tu Yuan-hang,Liao Wei-lin,Xu Zhao-hui.Synthesis of 9,9-bis(methoxymethyl)fluorene and its application[J].Jiangxi Chemical Industry,2008(4):117-120. |
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| Authors: | Xiong Bin Tu Yuan-hang Liao Wei-lin Xu Zhao-hui |
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| Affiliation: | Xiong Bin Tu Yuan-hong Liao Wei-lin Xu Zhao-hui(Fine Chemical Key Laborary of JiangXi Province Nanchang Jiangxi 330027 China) |
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| Abstract: | There are two steps in the synthesis of 9,9-bis(methoxymethyl)fluorene.Firstly,An intermediate,namely 9,9-bis(hydromethyl)fluorene was synthesized through the reaction between fluorene and paraformaldehydeas a catalyst of sodium ethylate.Then 9,9-bis(hydromethyl)fluorene reacted with NaOH and CH3Cl to synthesize the end product of 9,9-bis(methoxymethyl)fluorene by the phase transfer catalyst of tetrabutylammonium bromide(TBAB).Stucture of 9,9-bis(hydromethyl)fluorene was characterized by means of FT-IR and ... |
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| Keywords: | -bis(methoxymethyl)fluorene 9 9-bis(hydromethyl)fluorene electron donor phase transfer catalysis |
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