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一种新型两性界面活性剂的减阻特性
引用本文:魏进家,川口靖夫,David J.Hart. 一种新型两性界面活性剂的减阻特性[J]. 化工学报, 2006, 57(11): 2750-2754
作者姓名:魏进家  川口靖夫  David J.Hart
作者单位:西安交通大学动力工程多相流国家重点实验室, 陕西 西安 710049;东京理科大学机械工程系,日本千叶县, 2788510;俄亥俄州立大学化学系,美国俄亥俄州,43210 ;
基金项目:国家自然科学基金 , 教育部留学回国人员科研启动基金
摘    要:对一种新合成的两性界面活性剂N,N,N-三甲胺-N′-油酸酰亚胺在二维通道内的减阻特性进行了实验研究.为了能进行低温测试,以20%的甘醇不冻液为溶剂.溶液质量浓度范围为(5×10-5)~(1×10-3),测试温度为-5℃和25℃.用粒子成像测速仪对减阻流动的湍流特性进行了测量.实验表明,这种新型界面活性剂溶液呈现明显减阻特性,且减阻特性与浓度和温度均有很大的关系,最大减阻值可高达83%.该界面活性剂中加入NaNO2,在低温和低浓度条件下能有效改善减阻效果,而在常温和高浓度条件下反而降低减阻效果.添加界面活性剂抑制了湍流速度脉动和湍流涡脉动,使雷诺剪切应力完全消失.

关 键 词:新型  两性界面活性剂  减阻  湍流特性
文章编号:0438-1157(2006)11-2750-05
收稿时间:2005-09-28
修稿时间:2005-09-282005-12-15

Drag-reduction characteristics of a novel zwitterionic surfactant solution
WEI Jinjia,Kawaguchi Yasuo,David J.Hart. Drag-reduction characteristics of a novel zwitterionic surfactant solution[J]. Journal of Chemical Industry and Engineering(China), 2006, 57(11): 2750-2754
Authors:WEI Jinjia  Kawaguchi Yasuo  David J.Hart
Abstract:Experiments were conducted to study the drag-reduction characteristics of a newly synthesized zwitterionic surfactant solution (oleyl trimethylaminimide) in a two-dimensional channel.Ethylene glycol aqueous solution (EG/W) with mass fraction of 20% was used as solvent for measurements at subzero temperatures.The surfactant mass concentration ranged from 5×10-5 to 1×10-3, and the temperature was -5℃ and 25℃ respectively.Turbulence features of the surfactant drag-reducing flow were also measured by using particle image velocimetry (PIV) technique.It was found that the novel zwitterionic surfactant solution showed drag-reduction characteristics which were greatly affected by both concentration and temperature.The maximum drag-reduction could reach 83%.The addition of NaNO2 to the novel surfactant solution could improve the drag-reduction performance at low temperatures and concentrations, whereas it had a negative effect at high temperatures and concentrations.Turbulent velocity and vortex fluctuations were suppressed and Reynolds shear stress was diminished by adding surfactants into the turbulent flow.
Keywords:novel  zwitterionic surfactant   drag-reduction   turbulence characteristics
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