| 净化黄磷尾气变换制甲醇合成气工艺比较与选择 |
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| 引用本文： | 戴春皓,田森林,宁平,蒋蕾,莫虹.净化黄磷尾气变换制甲醇合成气工艺比较与选择[J].昆明理工大学学报(理工版),2007,32(6):70-73,94. |
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| 作者姓名： | 戴春皓 田森林 宁平 蒋蕾 莫虹 |
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| 作者单位： | 昆明理工大学,环境科学与工程学院,云南,昆明,650093 |
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| 基金项目： | 国家高技术研究发展计划(863计划);国家自然科学基金 |
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| 摘 要： | 为选择黄磷尾气变换制甲醇合成气的可行工艺流程，分析黄磷尾气部分变换制H2的不同工艺，即全量变换、部分变换、部分循环变换．根据黄磷尾气及所制合成气的特点，通过热量及变换率计算，选取部分循环进气方式变换制甲醇合成气，并通过中试试验验证黄磷尾气制合成气采取部分循环进气的方式可行且连续、可控．
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| 关 键 词： | 黄磷尾气 烟气净化 合成气 |
| 文章编号： | 1007-855X（2007）06-0070-04 |
| 收稿时间： | 2007-05-04 |
| 修稿时间： | 2007年5月4日 |
Comparison and Selection of Preparation Process of Methanol Synthesis Gas by Partial Conversion of Purified Yellow Phosphorus Off - Gas |
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| DAI Chun-hao,TIAN Sen-lin,NING Ping,JIANG Lei,MO Hong.Comparison and Selection of Preparation Process of Methanol Synthesis Gas by Partial Conversion of Purified Yellow Phosphorus Off - Gas[J].Journal of Kunming University of Science and Technology(Natural Science Edition),2007,32(6):70-73,94. |
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| Authors: | DAI Chun-hao TIAN Sen-lin NING Ping JIANG Lei MO Hong |
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| Abstract: | Different techniques of preparation of synthesis gas by partial conversion of purified yellow phosphorus off - gas are analyzed in this paper for the purpose of selecting a feasible process for preparation of methanol synthesis gas. The techniques include entire quantity conversion, part conversion and part cyclic conversion. Based on the characteristics of the off - gas and its converted synthesis gas, the circular conversion is selected through careful calculations of heat and conversion rate. It is proved that the circular heating method by using burning gas of purified yellow phosphorus off gas is feasible for preparation of methanol synthesis gas. |
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| Keywords: | yellow phosphorus off- gas flue gas purification synthesis gas |
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