| 分子氧/乙醛/过渡金属盐体系氧化环己烯的研究 |
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| 引用本文： | 宋国强,郑晓林,陶菊凤. 分子氧/乙醛/过渡金属盐体系氧化环己烯的研究[J]. 化工进展, 2004, 23(6): 638-640 |
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| 作者姓名： | 宋国强 郑晓林 陶菊凤 |
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| 作者单位： | 江苏工业学院化学工程系,常州,213016;常州市新北区环保局,常州,213022 |
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| 摘 要： | 采用分子氧／乙醛／过渡金属盐催化剂体系氧化环己烯合成环氧环己烷，此方法与传统的有机过氧化物氧化的方法相比，具有安全、简便、高效的特点。通过对影响此反应的过渡金属盐催化剂种类、用量以及反应物配比等主要因素的考察，可使氧化反应产物1，2-环氧环己烷的收率最高可达78．2％。
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| 关 键 词： | 分子氧 乙醛 环己烯 环氧环己烷 氧化反应 |
| 文章编号： | 1000-6613(2004)06-0638-03 |
| 修稿时间： | 2004-01-06 |
Studies on Oxidation of Cyclohexene by Molecular Oxygen/Acetaldehyde/Transition Metal Salts System Progress of Simulated Moving-bed Technology |
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| Song Guoqiang,Zheng Xiaolin,Tao Jufeng. Studies on Oxidation of Cyclohexene by Molecular Oxygen/Acetaldehyde/Transition Metal Salts System Progress of Simulated Moving-bed Technology[J]. Chemical Industry and Engineering Progress, 2004, 23(6): 638-640 |
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| Authors: | Song Guoqiang Zheng Xiaolin Tao Jufeng |
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| Affiliation: | Song Guoqiang1,Zheng Xiaolin1,Tao Jufeng2 |
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| Abstract: | The exploxidation of cyclohexene was achieved by the catalysis of transition metal salts with molecular oxygen in presence of aldehyde under mild conditions. The method is safer and very convenient in high yield, compared with the traditional oxidizing reagents. Some effects of several factors on the reaction were investigated such as the type of catalyst, the ratio of reactants etc. The yield of cycloexeneoxide reached 78 2%. |
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| Keywords: | molecular oxygen acetaldehyde cyclohexene epoxycyclohexane oxidation |
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