Nd3+ doped fluorochlorozirconate glass:3.9 μm MIR emission properties and energy transfer |
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引用本文: | 晏明,张晓松,李岚,莫兆军,金含,丁琪,丁文龙.Nd3+ doped fluorochlorozirconate glass:3.9 μm MIR emission properties and energy transfer[J].光电子快报,2017,13(5):344-348. |
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作者姓名: | 晏明 张晓松 李岚 莫兆军 金含 丁琪 丁文龙 |
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摘 要: | The Nd3+ doped fluorochlorozirconate (FCZ) glass was prepared by melt-quenching method. The 3.9 μm emission from Nd3+ ions is attributed to the two-photon absorption process. The strong emission transition at 3.9 μm fluorescence peak intensity, corresponding to the 4G11/2→2K13/2 transition, is directly proportional to the NaCl concentration. With the increase of the Cl- ions amount, the mid-infrared (MIR) luminescent intensity is significantly enhanced. Additionally, the Judd-Ofelt (J-O) parameter Ω2 is larger than that of the fluorozirconate (FZ) glass, which indicates the covalency of the bond between RE ions and ligand is stronger as Cl- ions substitution of F- ions in chloride FZ glass. The X-ray diffraction (XRD) patterns show that the amorphous glassy state keeps the FZ glass network structure. In brief, the advantageous spectroscopic characteristics make the Nd3+-doped FCZ glass be a promising candidate for application of 3.9 μm emission.
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收稿时间: | 2017/5/11 0:00:00 |
修稿时间: | 2017/6/14 0:00:00 |
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