| N-硝基-2,6-二硝基-4-三氟甲基苯胺类化合物的合成及其活性 |
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| 引用本文： | 江洪,方利,崔燕,陈长水.N-硝基-2,6-二硝基-4-三氟甲基苯胺类化合物的合成及其活性[J].农药,2008,47(1):26-28. |
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| 作者姓名： | 江洪 方利 崔燕 陈长水 |
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| 作者单位： | 华中农业大学,化学系,武汉,430070 |
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| 基金项目： | 国家自然科学基金
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华中农业大学博士基金 |
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| 摘 要： | 3,5-二硝基-4-氯三氟甲苯与胺反应生成2,6-二硝基-4-三氟甲基苯胺,以乙酰硝酸酯作硝化剂,代替直接以发烟硝酸作硝化剂,浓硫酸作溶剂,合成N-硝基-2,6-二硝基-4-三氟甲基苯胺.产物结构经IR、1H NMR、质谱、元素分析表征.生测结果表明目标产物对水稻和油菜有一定的生长调节作用.
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| 关 键 词： | N-硝基取代苯胺 硝化 调节作用 |
| 文章编号： | 1006-0413（2008）01-0026-03 |
| 收稿时间： | 2007-08-06 |
| 修稿时间： | 2007年8月6日 |
Synthesis of N-Nitro-2,6-dinitro-4-trifluoromethylanilines and Their Plant Regulating Activities |
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| JIANG Hong,FANG Li,CUI Yan,CHEN Chang-shui.Synthesis of N-Nitro-2,6-dinitro-4-trifluoromethylanilines and Their Plant Regulating Activities[J].Pesticides,2008,47(1):26-28. |
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| Authors: | JIANG Hong FANG Li CUI Yan CHEN Chang-shui |
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| Abstract: | 3,5-Dinitro-4-chlorotrifluoromethane reacted with amines produced 2,6-dinitro-4-trifluoromethylanilines. N-Nitro-2,6-dinitro-4-trifluoromethylanilines were prepared by nitration of 2,6-dinitro-4-trifluoromethylaniline in concentrated sulfuric acid with acetyl nitrate instead of directly using nitric acid as nitrating agent. Their structures were confirmed by IR,^1H NMR, MS spectra and elemental analyses, The biological test results showed that the target compounds have some regulating effects on rice and rape, |
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| Keywords: | phenylnitramine nitration regulating effect |
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