| N—(对硝基苯基)—N’—(甲氧基羰基)硫脲及其铜(Ⅰ)配合物的NMR研究 |
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| 引用本文： | 吴达旭,沈旭.N—(对硝基苯基)—N’—(甲氧基羰基)硫脲及其铜(Ⅰ)配合物的NMR研究[J].福建分析测试,1998(1). |
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| 作者姓名： | 吴达旭 沈旭 |
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| 作者单位： | 中国科学院福建物质结构研究所，中国科学院福建物质结构研究所 结构化学国家重点实验室 福州 350002，结构化学国家重点实验室 福州 350002 |
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| 摘 要： | 利用~1H—~1H COSY,HMQC等2D NMR技术对一种新的配体N—(对硝基苯基)—N’—(甲氧基羰基)硫脲(H_2pmt(Ⅰ)进行~1H、~(13)C NMR谱数据分析与归属;对于它与Cu~+离子配位的化合物Cu(H_2pmt)_2Cl(2)也作了~1H、~(13)C NMR的测定,归属了它们的所有谱线,对于它们的化学位移与配位行为作了简单讨论。
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| 关 键 词： | N-(对硝基苯基)-N’-(甲氧基在羰基)硫脲(H_2pmt) 铜(I)配合物 核磁共振波谱(NMR) |
NMR Studies on N-(p-nitrophenyl)-N'-(methoxycarbonyl) thiourea and its Cu (Ⅰ) Complex |
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| Wu Daxu Shen Xu.NMR Studies on N-(p-nitrophenyl)-N'-(methoxycarbonyl) thiourea and its Cu (Ⅰ) Complex[J].Fujian Anal Ysis & Testing,1998(1). |
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| Authors: | Wu Daxu Shen Xu |
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| Abstract: | In this paper ~1H、~(13)C NMR spectra of the thiourea derivatives N-(Pnitrophenyl)—N'—(ethoxycarbonyl) thiourea (H_2pet) (1) and its copper (Ⅰ ) complex Cu (H_2pet)_2Cl (2) were reported The ~1H-~1H COSY and HMQC spectra of complexes (1) were determined also. The spectral lines of all protons and carbons of the compounds were assigned. The relation between chemical shifts and coordination behavior of the complexes was briefly discussed. |
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| Keywords: | N-(p-nitrophenyl) -N'-(methoxycarbonyl) thiourea(H_2pmt) Cu(Ⅰ)complex |
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