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PS/P(BA-BOA)核壳乳液的研究
引用本文:徐祖顺,易昌凤,李晓琴,路国红,程时远,陈中华.PS/P(BA-BOA)核壳乳液的研究[J].高分子材料科学与工程,1996(6).
作者姓名:徐祖顺  易昌凤  李晓琴  路国红  程时远  陈中华
作者单位:湖北大学化学系,武汉军事经济学院军需系
摘    要:以丁氧基甲基丙烯酰胺(BOA)为活性单体,采用种子乳液聚合法制备了PS/P(BA-BOA)核壳型复合乳液,用透射电子显微镜观察了乳液粒子的微观形态,探讨了聚合方式等对微观结构的影响,对乳液的稳定性以及乳液膜的力学性能进行了测试,考察了聚合方式对乳液性能的影响。

关 键 词:聚合物乳液,PS/PBA乳液,乳液聚合,活性单体

STUDY ON CORE/SHELL EMULSION FOR POLYSTYRENE/ P (BUTYLACRYLATE BUTOXYMETHYLACRYLAMIDE)
Xu Zushun,Yi Changfeng,Li Xiaoqin,Lu Guohong,Cheng Shiyuan.STUDY ON CORE/SHELL EMULSION FOR POLYSTYRENE/ P (BUTYLACRYLATE BUTOXYMETHYLACRYLAMIDE)[J].Polymer Materials Science & Engineering,1996(6).
Authors:Xu Zushun  Yi Changfeng  Li Xiaoqin  Lu Guohong  Cheng Shiyuan
Abstract:PS/P(BA BOA) core/shell composite eumlsion were prepared by seed emulsion polymerization. The morphologies of particles have been characterized by TEM. The effects of polymerization methods on the structure of particles were investigated; moreover, the stability property of copolymer emulsion and the mechanical property of its film were studied. It has been found that the structures of composite emulsion particles were core/shell structure, the morphologies of composite emulsion particles were affected by polymerizatioin methods, emulsifier content, the stabilities of composite emulsion were increasing with the increase of N butoxymethylacrylamide content, the tensile strength of copolymer film which was prepared by semi continuous methods was the biggest of three methods.
Keywords:core/shell emulsion  emulsion polymerization  active monomer  PS/PBA latexes  
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