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节能灯PBT材料阻燃、增韧与抗黄变研究
引用本文:才勇,孟成铭,杨涛.节能灯PBT材料阻燃、增韧与抗黄变研究[J].工程塑料应用,2012,40(4):9-12.
作者姓名:才勇  孟成铭  杨涛
作者单位:上海日之升新技术发展有限公司技术中心,上海,201109
摘    要:研究了节能灯用玻璃纤维(GF)增强阻燃聚对苯二甲酸丁二酯(PBT)材料,分别探讨了新的阻燃体系,不同丙烯酸酯类增韧剂对其影响和材料的抗黄变问题。结果表明,新的阻燃体系溴代三嗪/三氧化二锑/OMMT阻燃效果较好,增韧剂中丙烯酸酯类接枝甲基丙烯酸缩水甘油酯(GMA)AX8900效果最好,其次为核壳结构丙烯酸酯类2M,最差为接枝MAH的丙烯酸酯类3M,但三者增韧效果差距不明显。抗黄变母粒的添加使得GF增强阻燃PBT材料在氙灯老化试验后颜色基本不变黄。

关 键 词:聚对苯二甲酸丁二酯  阻燃剂  增韧剂  抗黄变

Study on Flame Retardant, Toughness and Anti-Yellow of PBT Composites in Energy Saving Lamp
Cai Yong , Meng Chengming , Yang Tao.Study on Flame Retardant, Toughness and Anti-Yellow of PBT Composites in Energy Saving Lamp[J].Engineering Plastics Application,2012,40(4):9-12.
Authors:Cai Yong  Meng Chengming  Yang Tao
Affiliation:(Shanghai Sunny New Technology Development Co.Ltd,Shanghai 201109,China)
Abstract:Energy-saving lamp used glass fiber(GF) reinforced flame retardant polybutylene terephthalate(PBT)composites were studied,the impact of new flame retardant system and different acrylate toughening agent on composites and their anti-yellow problem were respectively investigaged.The results showed that new flame retardant system of brominated triazine/antimony trioxide/OMMT possessed better flame resistance,acrylate grafted glycidyl methacrylate(GMA) AX8900 had better toughening effect than core-shell structure acrylate 2M and MAH grafted acrylate 3M,but toughening effect gap among them was not obvious.Flame retardant PBT composites added with anti-yellow masterbatch showed essentially the same color after xenon lamp aging test.
Keywords:polybutylene terephthalate  flame retardant  toughening agent  anti-yellow
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