Affiliation: | 1. Laboratory of Infrared Materials and Devices, The Research Institute of Advanced Technologies, Ningbo University, Ningbo, China
Key Laboratory of Photoelectric Detection Materials and Devices of Zhejiang Province, Ningbo University, Ningbo, China;2. Laboratory of Infrared Materials and Devices, The Research Institute of Advanced Technologies, Ningbo University, Ningbo, China;3. Laboratory of Glasses and Ceramics, UMR 6226 CNRS-University of Rennes 1, Rennes Cedex, France;4. Department of Physics, National University of Singapore, Singapore City, Singapore |
Abstract: | The microhardness of chalcogenide glasses (ChGs) of the Sn–Sb–Se (SSS) ternary system was investigated, and the correlation of microhardness with the mean coordination number of the SSS ChGs was determined. To prepare infrared-transparent SSS glass-ceramics (GCs), two SSS ChGs (A, Sn6.23Sb14.11Se79.66; B, Sn9.8Sb17.22Se72.98; by molar composition) were selected and thermally treated at 433 and 448 K, respectively. The improved microhardness (with values that increased by 11.5% and 7.3% for SSS ChG A and B, respectively) of the resulting SSS GCs is attributed to the formation of Sb2Se3 nanocrystals. |