| Affiliation: | 1. Department of Inorganic Chemistry, Faculty of Natural Sciences, Comenius University in Bratislava, Bratislava, Slovakia;2. Faculty of Science and Technology, Keio University, Yokohama, Japan;3. Institute of Physical Chemistry and Electrochemistry, Leibniz Universität Hannover, Hannover, Germany;4. Department of Inorganic Chemistry, Faculty of Natural Sciences, Comenius University in Bratislava, Bratislava, Slovakia
Department of Magnetometry, Institute of Measurement Science, Slovak Academy of Sciences, Bratislava, Slovakia;5. Institute of Chemistry, Faculty of Natural Sciences, Comenius University in Bratislava, Bratislava, Slovakia;6. Institute of Nanotechnology, Karlsruhe Institute of Technology, Eggenstein-Leopoldshafen, Germany |
| Abstract: | Starting from gelatinous aluminum chloride hydroxide, the transformation process toward α-Al2O3 was examined using 27Al NMR, both in the liquid and solid states, as a main analytical tool. By increasing the hydrolysis ratio (h, defined as OH?]/Al3+]) of the starting aqueous precursor up to h = 2.5, the transition temperature to the final product, α-Al2O3, decreased to as low as 500°C. In this case, the structural change from amorphous alumina to α-Al2O3 took place without intermediate transition Al2O3 phases. Examining the process of networking during the transition from aqueous sol–through the state of xerogel–to final anhydrous oxide by nuclear magnetic resonance (NMR) revealed the presence of highly polymeric species mainly ascribed to δ-Al2O8Al28(OH)56(H2O)24]18+ (δ-Al30). δ-Al30 species were found in the solution phase and became predominant after drying. We conclude that the lower temperature synthesis of α-Al2O3 became possible due to preformation of polymerized AlO6 construction units in the precursor, reducing the energy barrier for the nucleation of the final α-Al2O3 phase. |
