Thermal and crystallization behavior of SiO2-PbF2 glass system in the presence of ErF3 and Al2O3

Oxyfluoride glass-ceramics have been introduced as one of the best bulk hosts for upconversion process of rare-earth ions. However, less attention to the technological topics in the process of glass crystallization has hindered the development of them in industrial scale applications. In this research, SiO₂–PbF₂ glasses were investigated to clarify the ambiguous role of rare-earth ions and alumina content in the microstructure and crystallization behavior. Results indicated that Er³⁺ addition caused a liquid-liquid phase separation via nucleation and growth mechanism, which led to single phase crystallization of β-PbF₂:Er³⁺ solid solution. Moreover, Er³⁺ had a significant effect on the crystallite size, size distribution, and PbF₂ crystallization temperature. On the other hand, increasing Al₂O₃ content enhanced the transparency and thermal stability of glass samples, whereas it reduced the amount of fluorine loss and increased the dissolution of Er³⁺ in fluoride crystalline structure. These results address some of the most controversial issues about crystallization behavior of rare-earth-doped oxyfluoride glasses.