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无氟连铸保护渣流变特性的研究
引用本文:王杏娟,武宾宾,朱立光,樊亚鹏,田阔.无氟连铸保护渣流变特性的研究[J].钢铁钒钛,2017,38(4).
作者姓名:王杏娟  武宾宾  朱立光  樊亚鹏  田阔
作者单位:华北理工大学冶金与能源学院,河北省现代冶金技术重点实验室,河北省高品质钢连铸工程技术研究中心,河北唐山063009
基金项目:国家自然科学青年基金项目,河北省自然科学基金项目
摘    要:利用现场生产用原料配置保护渣基样,分别以B_2O_3、TiO_2作为CaF_2的替代物,测定了不同含量CaF_2、TiO_2、B_2O_3保护渣的黏度和转折温度,绘制了相应的lnη-1/T曲线图,并进行拟合计算得到了其黏流活化能。深入分析了保护渣中CaF_2、TiO_2、B_2O_3含量的变化趋势及对保护渣流变特性影响的内在原因,得出了适宜流变特性的无氟保护渣中合理的TiO_2、B_2O_3含量,保护渣内的TiO_2含量不超过9%,B_2O_3含量不超过7%。

关 键 词:连铸  无氟保护渣  黏度  黏流活化能  熔化温度  转折温度

Study on Rheological Properties of Fluorine-free Continuous Casting Mould Powder
Wang Xingjuan,Wu Binbin,Zhu Liguang,Fan Yapeng,Tian Kuo.Study on Rheological Properties of Fluorine-free Continuous Casting Mould Powder[J].Iron Steel Vanadium Titanium,2017,38(4).
Authors:Wang Xingjuan  Wu Binbin  Zhu Liguang  Fan Yapeng  Tian Kuo
Abstract:In this paper the transition temperature and viscosity of mould powder with different B2O3,TiO2 and CaF2 had been measured,and the corresponding lnη-1 / T curve had been plotted.Viscous flow activation energy had been calculated through fitting method.The effect of CaF2,TiO2 and B2O3 contents on the rheology characteristics of mould powder had been investigated.The reasonable TiO2 and B2O3 contents for appropriate rheological properties of mould powder without fluorine are less than 9% and 7%,respectively.
Keywords:continuous casting  mold powder  fluorine  viscosity  viscous flow activation energy flux
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