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Effects of B addition on glass forming ability and thermal behavior of FePC-based bulk metallic glasses
Authors:Sheng-feng Guo  Chen Su  Jia-xiang Cui  Jing Li  Guan-nan Li  Meng Zhang  Ning Li
Affiliation:1. Faculty of Materials and Energy, Southwest University, Chongqing 400715, China;2. Institute of Advanced Wear &Corrosion Resistant and Functional Materials, Jinan University, Guangzhou 510632, Guangdong, China;3. School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, Hubei, China
Abstract:The FePC-based bulk metallic glasses (BMGs) have been demonstrated to possess high plasticity and good soft magnetic properties.However, the relatively poor glass forming ability (GFA) and thermal stabilities limited their application in industries.The effects of microalloying with B in FePC-based BMGs on the GFA and thermal behaviors were systematically investigated.It was found that a small amount of B addition can dramatically enhance the GFA of FePC-based BMGs, which in turn leads to the critical maximum diameter up to 2 mm for full glass formation even using low cost raw materi-als.The underlying mechanism of the enhancement of GFA from the competing crystalline phase with amorphous phase, the average thermal expansion coefficient and dynamic viscosity were dis-cussed in detail.
Keywords:Fe-based bulk metallic glass  Glass forming ability  Thermal behavior  Thermal expansion coefficient  Dynamic viscosity  B addition
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