| 冷却速度时Ml（NiCoMoTi）5贮氢合金电化学性能的影响 |
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| 引用本文： | 李传健,王新林,李岫梅,王崇愚.冷却速度时Ml（NiCoMoTi）5贮氢合金电化学性能的影响[J].金属学报,1998,34(3):288-292. |
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| 作者姓名： | 李传健 王新林 李岫梅 王崇愚 |
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| 作者单位： | 冶金工业部钢铁研究总院新材料研究所;北京,100081;冶金工业部钢铁研究总院新材料研究所;北京,100081;冶金工业部钢铁研究总院新材料研究所;北京,100081;冶金工业部钢铁研究总院新材料研究所;北京,100081 |
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| 基金项目： | 国家863计划资助!861-715-004-0230 |
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| 摘 要： | 对不同冷却速度下制成的具有同一成分的贮氢合金做了电化学充放电循环实验，比较了它们的容量、电化学循环稳定性及放电电压性能。高的冷却速度导致放电容量的特别是大电流放电容量较大幅度下降，活化困难，放电电压也有所降低，但改善了合金的循环稳定性及放电电压平台特性。
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| 关 键 词： | 稀土 AB5 贮氢合金 冷却速度 电化学性能 |
| 收稿时间： | 1998-03-18 |
| 修稿时间： | 1998-03-18 |
THE EFFECT OF CAST RATE ON THE ELECTROCHEMICAL PROPERTIES OF Ml(NiCoMnTi)_5 HYDROGEN STORAGE ALLOY |
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| LI Chuanjian,WANG Xinlin,LI Xiumei,WANG Chongyu.THE EFFECT OF CAST RATE ON THE ELECTROCHEMICAL PROPERTIES OF Ml(NiCoMnTi)_5 HYDROGEN STORAGE ALLOY[J].Acta Metallurgica Sinica,1998,34(3):288-292. |
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| Authors: | LI Chuanjian WANG Xinlin LI Xiumei WANG Chongyu |
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| Affiliation: | LI Chuanjian,WANG Xinlin,LI Xiumei,WANG Chongyu (Advanced Materials Institute,Central Iron & Steel Research Institute,Beliing ) |
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| Abstract: | Electrochemical charge-discharge-cycling measurements were made on electrode samples prepared from alloys of the same composition with different solidification rates,and their discharge capacity, cycle stability, discharge voltage characteristics were compared.High solidification rates could improve greatly the stability and discharge voltage property, but also lead to a decrease in capacity, especially the high discharge rate capability. All alloys in as-quenched state were generally much more difficult to activate completely. |
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| Keywords: | rare earth AB5 hydrogen-storage alloy negative electrode solidilication rate electrochemical property |
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