Solid-state hydrogen storage: Storage capacity,thermodynamics, and kinetics |
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Authors: | William Osborn Tippawan Markmaitree Leon L Shaw Ruiming Ren Jianzhi Hu Ja Hun Kwak Zhenguo Yang |
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Affiliation: | (1) Department of Chemical, Materials and Biomolecular Engineering, University of Connecticut, Storrs, CT 06269, USA;(2) School of Materials Science and Engineering, Dalian Jiaotong University, Dalian, China;(3) Pacific Northwest National Laboratory, Richland, Washington, USA |
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Abstract: | Solid-state reversible hydrogen storage systems hold great promise for onboard applications. The key criteria for a successful
solid-state reversible storage material are high storage capacity, suitable thermodynamic properties, and fast hydriding and
dehydriding kinetics. The LiNH2 + LiH system has been utilized as an example system to illustrate these critical issues that are common among other solid-state
reversible storage materials. The progress made in thermodynamic destabilization and kinetic enhancements via various approaches
are emphasized. The implications of these advancements in the development of future solid-state reversible hydrogen storage
materials are discussed. |
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