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Solid-state hydrogen storage: Storage capacity,thermodynamics, and kinetics
Authors:William Osborn  Tippawan Markmaitree  Leon L Shaw  Ruiming Ren  Jianzhi Hu  Ja Hun Kwak  Zhenguo Yang
Affiliation:(1) Department of Chemical, Materials and Biomolecular Engineering, University of Connecticut, Storrs, CT 06269, USA;(2) School of Materials Science and Engineering, Dalian Jiaotong University, Dalian, China;(3) Pacific Northwest National Laboratory, Richland, Washington, USA
Abstract:Solid-state reversible hydrogen storage systems hold great promise for onboard applications. The key criteria for a successful solid-state reversible storage material are high storage capacity, suitable thermodynamic properties, and fast hydriding and dehydriding kinetics. The LiNH2 + LiH system has been utilized as an example system to illustrate these critical issues that are common among other solid-state reversible storage materials. The progress made in thermodynamic destabilization and kinetic enhancements via various approaches are emphasized. The implications of these advancements in the development of future solid-state reversible hydrogen storage materials are discussed.
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