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制备W-Ni-Cu钨合金的热解还原法工艺探讨
引用本文:梁容海,王伏生,周载明,易富德,高宏伟. 制备W-Ni-Cu钨合金的热解还原法工艺探讨[J]. 稀有金属与硬质合金, 1994, 0(3)
作者姓名:梁容海  王伏生  周载明  易富德  高宏伟
作者单位:中南工业大学
摘    要:用硝酸镍、氯化铜与乙酸镍、乙酸铜的溶液分别与钨粉混合,干燥,经热解还原法制备的W-Ni-Cu钨合金,其技术指标均可满足使用要求。文章分析、讨论了这两种工艺特性及存在的问题。采用硝酸镍、氯化铜代镍、铜所制备的钨合金,在热解还原过程中产生大量有毒气体、严重的污染环境。乙酸镍、乙酸铜代镍和铜制备的钨合金,在热解还原过程中较好地解决了对环境及产品的污染问题,并保持了热解还原工艺的特性。

关 键 词:热解还原法,钨合金

Study on Thermal Decomposition-Reduction Process for Preparing W-Ni-Cu Tungsten Alloys
Liang Roughai, Wang Fusheng, Zhou Zaiming, Yi Fude, Gao Hongwei. Study on Thermal Decomposition-Reduction Process for Preparing W-Ni-Cu Tungsten Alloys[J]. Rare Metals and Cemented Carbides, 1994, 0(3)
Authors:Liang Roughai   Wang Fusheng   Zhou Zaiming   Yi Fude   Gao Hongwei
Affiliation:Central-south University of Technology
Abstract:W-Ni-Cu Tungsten alloys can be produced by the thermal decomposition-reduction of the W powder mixture with Ni(NO3)2, CuCl2solutions or with Ni(CH3COO)2, Cu(CH3COO)2 solutions. Both manufactured alloys are available for use. The characteristics and problems of the processes using two different mixtures were studied in details. It was clearly shown that the use of the first mixture during reduction results in a lot of toxic gases, which are harm to the environment, and the second mixture is favourable for environment protect and product quality during reduction.
Keywords:thermal decomposition-reduction   tungsten alloys
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