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糖蜜酒精废液中大分子焦糖色素模拟物浸出软锰矿的动力学
引用本文:粟海锋,吕奕菊,崔勍焱,王凡,吕小艳,文衍宣.糖蜜酒精废液中大分子焦糖色素模拟物浸出软锰矿的动力学[J].高校化学工程学报,2011,25(1):43-48.
作者姓名:粟海锋  吕奕菊  崔勍焱  王凡  吕小艳  文衍宣
作者单位:1. 广西大学,化学化工学院,广西,南宁,530004
2. 广西大学,教务处,广西,南宁,530004
基金项目:国家自然科学基金(20866001); 广西自然科学基金(桂科自0832035)
摘    要:用收缩芯模型研究了糖蜜酒精废液中大分子焦糖色素在硫酸介质中还原浸出软锰矿的动力学,考察了软锰矿粒度、反应温度、浸出时间、硫酸浓度和焦糖色素浓度对锰浸出速率的影响.结果表明锰浸出速率随反应温度、硫酸浓度、焦糖色素浓度的增加和软锰矿粒径的减小而增加.糖蜜酒精废液中大分子焦糖色素还原浸出软锰矿属固体产物层扩散控制,表观活化能...

关 键 词:软锰矿  糖蜜酒精废液  焦糖色素  浸出  动力学

Leaching Kinetics of Pyrolusite by Macromolecular Caramel of Molasses Alcohol Wastewater
SU Hai-feng,L Yi-ju,CUI Qing-yan,WANG Fan,L Xiao-yan,WEN Yan-xuan.Leaching Kinetics of Pyrolusite by Macromolecular Caramel of Molasses Alcohol Wastewater[J].Journal of Chemical Engineering of Chinese Universities,2011,25(1):43-48.
Authors:SU Hai-feng  L Yi-ju  CUI Qing-yan  WANG Fan  L Xiao-yan  WEN Yan-xuan
Affiliation:1(1.School of Chemistry and Chemical Engineering,Guangxi University,Nanning 530004,China; 2.Educational Administration Department,Guangxi University,Nanning 530004,China)
Abstract:In order to study using the macromolecular caramel in the molasses alcohol wastewater to leaching the manganese from a low grade pyrolusite,the shrinking core model was used to investigate the kinetics of the manganese reductive leaching process in dilute sulfate acid.Since the salvage of only the macromolecular caramel from the molasses alcohol wastewater is very difficult,in this study the synthesized caramel was used to simulate it.The effects of reaction temperature,the concentrations of H2SO4 and caram...
Keywords:pyrolusite  molasses alcohol wastewater  caramel  leaching  kinetics  
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