| 羧酸酯加氢金属催化剂研究进展 |
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| 引用本文： | 刘勇,李春迎,张伟,吕剑.羧酸酯加氢金属催化剂研究进展[J].化学试剂,2011,33(10):904-908. |
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| 作者姓名： | 刘勇 李春迎 张伟 吕剑 |
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| 作者单位： | 西安近代化学研究所,陕西西安,710065 |
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| 摘 要： | 羧酸酯通过催化加氢可以制备高附加值的醇、醛和酸,该类反应得到了广泛地研究.回顾了羧酸酯催化加氢所使用的金属催化剂,重点讨论了铜基催化剂、锰氧化物催化剂、贵金属铑、钌、铂和钯催化剂在羧酸酯加氢反应中的应用,并对羧酸酯加氢反应中环境友好的新型催化剂进行了展望.
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| 关 键 词： | 羧酸酯 催化加氢 金属催化剂 |
Progress of metal-catalyst hydrogenation of carboxylic acid esters |
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| LIU Yong,LI Chun-ying,ZHANG Wei,LV Jian.Progress of metal-catalyst hydrogenation of carboxylic acid esters[J].Chemical Reagents,2011,33(10):904-908. |
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| Authors: | LIU Yong LI Chun-ying ZHANG Wei LV Jian |
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| Abstract: | Alcohol,aldehyde and acid can be prepared via hydrogenation of carboxylic acid esters with metal-catalysis,and such reactions have been extensively studied for several decades.In this paper,catalysts including copper-based catalysts,manganese oxide catalysts,noble metal catalyst such as ruthenium,rhodium,platinum and Palladium used in the area of hydrogenation of carboxylic acid esters were reviewed in detail.Futhermore,the novel catalyst with environment-free is also prospected. |
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| Keywords: | carboxylic acid esters catalysis hydrogenation metal-catalyst |
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