| 六(4-醛基苯氧基)环三磷腈的合成、表征及其热性能研究 |
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| 引用本文： | 肖啸,甘孝贤,刘庆,韩涛,栗磊.六(4-醛基苯氧基)环三磷腈的合成、表征及其热性能研究[J].化学推进剂与高分子材料,2011,9(5):72-75. |
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| 作者姓名： | 肖啸 甘孝贤 刘庆 韩涛 栗磊 |
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| 作者单位： | 西安近代化学研究所,陕西西安,710065 |
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| 摘 要： | 通过六氯环三磷腈和4-羟基苯甲醛的亲核取代反应,成功合成出目标化合物六(4-醛基苯氧基)环三磷腈(HAPCP).并考察了溶剂和缚酸剂类型、缚酸剂粒度、原料配比及反应时间对产物收率的影响.利用红外光谱和核磁共振对目标化合物的结构进行了表征,同时用热失重分析研究了目标化合物的热稳定性.结果表明:目标化合物在400℃左右有明...
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| 关 键 词： | 包覆层 有机填料 耐热性 六(4-醛基苯氧基)环二磷腈 |
Researches on Synthesis,Characterization and Thermal Property of Hexakis(4-Formacylphenoxy) Cyclotriphosphazene |
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| XIAO Xiao,GAN Xiaoxian,LIU Qing,HAN Tao,LI Lei.Researches on Synthesis,Characterization and Thermal Property of Hexakis(4-Formacylphenoxy) Cyclotriphosphazene[J].Chemical Propellants & Polymeric Materials,2011,9(5):72-75. |
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| Authors: | XIAO Xiao GAN Xiaoxian LIU Qing HAN Tao LI Lei |
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| Affiliation: | XIAO Xiao,GAN Xiaoxian,LIU Qing,HAN Tao,LI Lei(Xi'an Modern Chemistry Research Institute,Xi'an 710065,China) |
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| Abstract: | The target compound hexakis(4-formacylphenoxy)cyclotriphosphazene(HAPCP) was successfully synthesized by nucleophilic substitution reaction of hexachlorotriphosphazene and 4-hydroxybenzyl aldehyde.The influence of the solvent and deacid reagent type,deacid reagent particle size,raw material ratio and reaction time on the yield of the product was investigated.The structure of the target compound was characterized by using FT-IR spectrum and NMR,and its thermal stability was studied by using thermal gravimetr... |
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| Keywords: | inhibitor organic filler heat resistance hexakis(4-formacylphenoxy) cyclotriphosphazene |
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