| 2,9,16,23-四叔丁基酞菁硅醚的合成 |
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| 引用本文： | 王莉,邓启华. 2,9,16,23-四叔丁基酞菁硅醚的合成[J]. 化学世界, 2013, 54(3): 172-174 |
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| 作者姓名： | 王莉 邓启华 |
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| 作者单位： | 1. 泸州职业技术学院机械工程系,四川泸州,646005
2. 四川化工职业技术学院制药与环境工程系,四川泸州,646005 |
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| 摘 要： | 4-叔丁基邻苯二腈在氨和甲醇钠作用下环合为5-叔丁基-1,3-二亚氨基异吲哚,然后在SiCl4作用下环合为二氯酞菁硅,经浓硫酸水解和三己基氯硅烷醚化,得到硅酞菁醚,产物总收率为58.6%。目标化合物结构经波谱分析进行确证。
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| 关 键 词： | 酞菁硅醚 二羟基硅酞菁 合成 |
Synthesis of Di(n-hexylsilyloxy) silicon 2,9,16,23-tetra-(t-butyl) phthalocyanine |
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| WANG Li,DENG Qi-hua. Synthesis of Di(n-hexylsilyloxy) silicon 2,9,16,23-tetra-(t-butyl) phthalocyanine[J]. Chemical World, 2013, 54(3): 172-174 |
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| Authors: | WANG Li DENG Qi-hua |
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| Affiliation: | 1.Mechanical Engineering Department of Luzhou Vocational and Technology College,Sichuan Luzhou 646005,China; 2.Pharmaceutical and Environmental Engineering Department of Sichuan Chemical Vocational and Technical College,Sichuan Luzhou 646005,China) |
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| Abstract: | Dihydroxy(phtha1ocyanino)silicon(3) was synthesized from 4-tert-butyl-1,2-dicyanobenzene by ammonolysis and cyclization,cyclization with SiCl4,and hydrolysis.(3) was etherificated with tri-n-hexylchlorosilane to afford the target compound(4).Its structure was determined by UV spectroscopy,1H NMR,and MS techniques. |
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| Keywords: | phthalocyaninosilicon ether dihydroxy(phthalocyano)silicon synthesis |
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