A one-pot approach to dendritic star polymers via double click reactions |
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| Authors: | Xing Q Xiong Yuan H Xu |
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| Affiliation: | (1) College of Materials Science & Engineering, Huaqiao University, 361021 Xiamen, China |
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| Abstract: | A class of well-defined dendritic star polymers with poly (ε-caprolactone) (PCLs) on the periphery has been prepared via one-pot
double click reactions (Cu-catalyzed azide/alkyne click chemistry, i.e., CuAAC and Diels–Alder 4+2] cycloaddition reactions).
The predecessors for Diels–Alder reaction, maleimide end-functionalized PCLs were produced by ring-opening polymerization
(ROP). Obtained dendritic star polymers were characterized by 1H NMR, size exclusion chromatography (SEC), UV/vis, and fluorescence spectroscopy. |
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