Suspension and solution thermal spray coatings |
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Authors: | Lech Pawlowski |
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Affiliation: | Service of Thermal Spraying at Ecole Nationale Supérieure de Chimie de Lille 8, avenue Mendeleïev, B.P. 90108, 59650 Villeneuve d'Ascq, France |
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Abstract: | The emerging methods of coating deposition by suspension and solution thermal spraying are described. The liquid suspensions of fine powders and liquid precursors are injected into flames and/or jets generated in the torches. The formulation and stability of suspensions as well as the methods of fine powders synthesis are briefly described. Typical solutions, being often the liquid organo-metallics are also briefly described. An important problem of injection of liquids into jets and flames is then presented. Two principal modes of injection, used at present, are outlined, i.e.: (i) atomization; and, (ii) injection of a continuous jet. Subsequently, the phenomena occurring in flames and plasma jets are discussed and the major differences to these occurring during conventional spraying are stressed up. The build up of coatings starting from the impact of fine particles on the substrate is described and typical microstructures of suspension and solution sprayed coatings are shown. Some properties of the sprayed coatings, including mechanical, electrical, chemical, and thermophysical ones are collected and presented. Finally, the emerging applications of coatings are shown and the possible future applications are discussed. |
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Keywords: | CEA, Commissariat à l'É nergie Atomique CVD, chemical vapour deposition DEA, diethanol amine Dc, direct current EMPA, electron microprobe analysis ENSCL, Ecole Nationale Supé rieure de Chimie de Lille HA, hydroxyapatite (Ca10(PO4)6(OH)2) HVOF, high velocity oxy-fuel ID, internal diameter IEP, isoelectric point M, Metal MOCVD, metallo-organic chemical vapour deposition PAA, polyacrylic acid PEI, polyethylene imine PBTCA, 2-phosphonobutane-1, 2, 4-tricarboxylic acid PVA, polyvinyl alcohol PVP, polyvinyl pyrolidine R, alkyl group, R = CxH2x + 1(CH3, C2H5&hellip ) Re, Reynolds number, defined in Eq. (1) RF, radio frequency SDC, Samaria doped ceria SPPS, suspension precursor plasma spraying SEM, scanning electron microscope SOFC, solid oxide fuel cell We, Weber number, defined in Eq. (3) TAB, Taylor analogy break-up TEM, transmission electron microscope YSZ, yttria stabilized zirconia |
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