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Suspension and solution thermal spray coatings
Authors:Lech Pawlowski
Affiliation:Service of Thermal Spraying at Ecole Nationale Supérieure de Chimie de Lille 8, avenue Mendeleïev, B.P. 90108, 59650 Villeneuve d'Ascq, France
Abstract:The emerging methods of coating deposition by suspension and solution thermal spraying are described. The liquid suspensions of fine powders and liquid precursors are injected into flames and/or jets generated in the torches. The formulation and stability of suspensions as well as the methods of fine powders synthesis are briefly described. Typical solutions, being often the liquid organo-metallics are also briefly described. An important problem of injection of liquids into jets and flames is then presented. Two principal modes of injection, used at present, are outlined, i.e.: (i) atomization; and, (ii) injection of a continuous jet. Subsequently, the phenomena occurring in flames and plasma jets are discussed and the major differences to these occurring during conventional spraying are stressed up. The build up of coatings starting from the impact of fine particles on the substrate is described and typical microstructures of suspension and solution sprayed coatings are shown. Some properties of the sprayed coatings, including mechanical, electrical, chemical, and thermophysical ones are collected and presented. Finally, the emerging applications of coatings are shown and the possible future applications are discussed.
Keywords:CEA, Commissariat à   l'É  nergie Atomique   CVD, chemical vapour deposition   DEA, diethanol amine   Dc, direct current   EMPA, electron microprobe analysis   ENSCL, Ecole Nationale Supé  rieure de Chimie de Lille   HA, hydroxyapatite (Ca10(PO4)6(OH)2)   HVOF, high velocity oxy-fuel   ID, internal diameter   IEP, isoelectric point   M, Metal   MOCVD, metallo-organic chemical vapour deposition   PAA, polyacrylic acid   PEI, polyethylene imine   PBTCA, 2-phosphonobutane-1, 2, 4-tricarboxylic acid   PVA, polyvinyl alcohol   PVP, polyvinyl pyrolidine   R, alkyl group, R     CxH2x     1(CH3, C2H5&hellip  )   Re, Reynolds number, defined in Eq. (1)   RF, radio frequency   SDC, Samaria doped ceria   SPPS, suspension precursor plasma spraying   SEM, scanning electron microscope   SOFC, solid oxide fuel cell   We, Weber number, defined in Eq. (3)   TAB, Taylor analogy break-up   TEM, transmission electron microscope   YSZ, yttria stabilized zirconia
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