| 大环配合物[Ni (14)4,11-二烯-N4)]Ⅰ2和Co((14)4,11-二烯-N4)]Ⅰ2的合成 |
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| 引用本文： | 刘云华,殷彩霞,张仙,刘海龙,赵艳,赵红梅,卜玉涛. 大环配合物[Ni (14)4,11-二烯-N4)]Ⅰ2和Co((14)4,11-二烯-N4)]Ⅰ2的合成[J]. 化学与生物工程, 2011, 0(11): 51-53 |
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| 作者姓名： | 刘云华 殷彩霞 张仙 刘海龙 赵艳 赵红梅 卜玉涛 |
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| 作者单位： | 云南农业大学基础与信息工程学院;云南大学化学科学与工程学院;云南农业大学经济管理学院; |
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| 摘 要： | 在酸性条件下,丙酮缩合成异丙基丙酮,再与乙二胺反应生成β-氨基酮,再与另一酮基缩合得到[(14)4,11-二烯-N4]2HI,最后分别与Ni(OAc)2·4H2O和Co(OAc)2·4H2O进行反应,得到大环配合物[Ni (14)4,11-二烯-N4)]Ⅰ2和[Co (14)4,11-二烯-N4)]Ⅰ2,其结构经IR、...
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| 关 键 词： | 钴 镍 大环配合物 大环配体 |
Study on Synthesis of Macrocyclic Complexes [Ni((14) 4,11-diene-N_4)]I_2 and [Co((14) 4,11-diene-N_4)]I_2 |
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| LIU Yun-hua,YING Cai-xia,ZHANG Xian,LIU Hai-long,ZHAO Yan,ZHAO Hong-mei,PU Yu-tao. Study on Synthesis of Macrocyclic Complexes [Ni((14) 4,11-diene-N_4)]I_2 and [Co((14) 4,11-diene-N_4)]I_2[J]. Chemistry & Bioengineering, 2011, 0(11): 51-53 |
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| Authors: | LIU Yun-hua YING Cai-xia ZHANG Xian LIU Hai-long ZHAO Yan ZHAO Hong-mei PU Yu-tao |
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| Affiliation: | LIU Yun-hua1,YING Cai-xia2,ZHANG Xian3,LIU Hai-long2,ZHAO Yan1,ZHAO Hong-mei1,PU Yu-tao1(1.College of Base and Information Engineering,Yunnan Agricultural University,Kunming 650201,China,2.College of Chemical Science and Engineering,Yunnan University,Kunming 650091,3.College of Economic and Management,China) |
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| Abstract: | In acidic conditions,acetone condensed to form isopropyl acetone then reacted with ethylenediamine to form β-amino ketone then condensed with another ketone to form[(14)4,11-diene-N4]2HI,and then respectively reacted with Ni(OAc)2·4H2O and Co(OAc)2·4H2O to form macrocyclic complexs[Ni((14) 4,11-diene-N4)]I2 and [Co((14) 4,11-diene-N4)]I2.Their structures were confirmed by IR,1HNMR,13CNMR. |
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| Keywords: | cobalt nickel macrocyclic complex macrocyclic ligand |
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