Fun with photons: selective light induced reactions in solution and in water soluble nano-containers |
| |
Authors: | Ayitou Anoklase Pemberton Barry C Kumarasamy Elango Vallavoju Nandini Sivaguru J |
| |
Affiliation: | North Dakota State University, Department of Chemistry and Biochemistry, 1231 Albrecht Blvd., 104H, LADD Hall, P.O. Box 6050, NDSU Dept 2735 Fargo, ND 58108-6050, USA. |
| |
Abstract: | Two distinct strategies for controlling selectivity, in particular stereoselectivity in photochemical reactions are reviewed. In the first strategy, supramolecular approach using cucurbituril nano-containers in catalytic amounts is employed to control selectivity during photochemical transformations. In the second approach, a generalized methodology for carrying out light-induced transformations in solution at ambient conditions is detailed where axially chiral motifs are employed to enantiospecifically transfer the axial chirality in the reactant to point chirality in the photoproduct(s). |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|