| 用杂多酸固载化催化剂催化酯化反应 |
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| 引用本文： | 王新平,毛海梅.用杂多酸固载化催化剂催化酯化反应[J].精细石油化工,1994(2):15-20. |
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| 作者姓名： | 王新平 毛海梅 |
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| 作者单位： | 中国科学院长春应用化学研究所，中国科学院长春应用化学研究所，中国科学院长春应用化学研究所，长春地质专科学校 吉林，130022，吉林，130022，吉林，130022 |
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| 摘 要： | 在液-固和气-固反应体系中,研究了固载在不同活性炭上的杂多酸催化剂对正丁醇和乙酸、乙醇和乙酸酯化反应的催化作用.实验表明,活性炭载体表面的磁性灰分对催化活性是不利的.不同活性炭对杂多酸的固载牢度显著不同,其中煤质炭较为理想.在液-固相合成乙酸丁酯和气-固相合成乙酸乙酯反应中,杂多酸/煤质炭催化剂的活性均高于HZSM-5分子筛和酸性大孔离子交换树脂.
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| 关 键 词： | 杂多酸固载催化剂 酯化反应 正丁醇 乙醇 乙酸 |
A STUDY OF THE ESTERIFICATION CATALYZED BY SUPPORTED HETEROPLY-ACID |
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| Wang Xinping,Ye Xingkai and Wu Yue Changchun Institute of Applied Chemistry,the Academy of Sciences of ChinaMao Haimei Changchun Geologic College.A STUDY OF THE ESTERIFICATION CATALYZED BY SUPPORTED HETEROPLY-ACID[J].Speciality Petrochemicals,1994(2):15-20. |
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| Authors: | Wang Xinping Ye Xingkai and Wu Yue Changchun Institute of Applied Chemistry the Academy of Sciences of ChinaMao Haimei Changchun Geologic College |
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| Abstract: | The catalytic action of heteropoly-acid(HPA)supported on active carbons was investigated during the esteri-fication of n-butanol and ethanol with acetic acid in the liquid-solid and the gas -solid systems separately. Experi-mental results indicated that the ash impurity of carbon supporters significantly decrease the catalytic activity of the HPA/C catalyst. Moreover,the active carbons studied had different adsorption strength for HPA,in which the carbons made from coal showed satisfactory results. Whether in synthesis of butylacetate in the liquid-solid system or in synthesis of ethylacetate in the gas-solid system,the catalytic activity of HPA/C(from coal)was much higher that of HZSM-5 zeolite and acidic macroporous ion exchange resin. |
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| Keywords: | :Supported Heteropoly-Acid Catalyst Esterification n-Butanol s Ethanol Acetic Acid |
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