| 微波萃取气相色谱法测定鱼肉中有机氯残留 |
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| 引用本文： | 郑林,施泽明,李佳宣,林清梅,倪师军.微波萃取气相色谱法测定鱼肉中有机氯残留[J].四川轻化工学院学报,2010(1):62-64,68. |
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| 作者姓名： | 郑林 施泽明 李佳宣 林清梅 倪师军 |
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| 作者单位： | [1]成都理工大学地球化学系,成都610051 [2]福建省核工业294大队,福州350013 |
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| 基金项目： | 中国地质调查局“成都经济区城市生态地球化学调查与评价”和国家环保部“汶川特大地震造成矿山破坏对农田土壤污染评估与应对措施”联合资助（200314200015） |
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| 摘 要： | 探索测定鱼肉中有机氯的快速、准确和价廉的方法。采用微波萃取技术提取鱼肉中的六六六、滴滴涕，再利用毛细管气相色谱分离，微电子捕获检测器检测。8种有机氯农药回收率在89．3％-104．2％之间，相对标准偏差均小于10％。说明准确度与精密度较好，符合农药残留量分析的基本要求。探索了各成分在不同食性鱼肉中的含量特征，结果显示：肉食性鱼类〉杂食性鱼类〉草食性鱼类。可见，有机氯农药随着食物链在生物体内富集。
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| 关 键 词： | 微波萃取 气相色谱 鱼 有机氯 |
Analysis of Organic Chlorinated Pesticides in Fish by Microwave Extraction/Capillary GC |
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| ZHENG Lin,SHI Ze-ming,LI Jia-xuan,LIN Qing-mei,NI Shi-jun.Analysis of Organic Chlorinated Pesticides in Fish by Microwave Extraction/Capillary GC[J].Journal of Sichuan Institute of Light Industry and Chemical Technology,2010(1):62-64,68. |
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| Authors: | ZHENG Lin SHI Ze-ming LI Jia-xuan LIN Qing-mei NI Shi-jun |
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| Affiliation: | 1. Department of Geochemistry, Chengdu University of Technology, Chengdu 610051, China; 2. No. 294 Geological Party of Fujian Provincial Nuclear Industry, Fuzhou 350013, China) |
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| Abstract: | The aim was to explore the quick, exact and cheap method for detection on fish. The organic chlorinated pesticides （ HCHs and DDTs） in fish were extracted by microwave extraction and analyzed by capillary GC with μECD. The extraction recovery was 89.3%-104. 2%, and RSD was less than 10%. Accuracy and precision which were better accorded to the requirements of analysis of pesticide residues. Explored the content characteristics of organochlorine in kinds of fish. The results showed that：flesh-eat fish 〉 omnivorous fish 〉 herbivorous fish. Obviously, organoehlorine pesticides enriched in the organisms body with the food chain. |
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| Keywords: | microwave extraction GC-ECD fish organochlorine |
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