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Separation of heavy metal ions bycomplexation on poly (N-vinyl imidazole)hydrogels
Authors:Nursel?Pekel  author-information"  >  author-information__contact u-icon-before"  >  mailto:nursel@hacettepe.edu.tr"   title="  nursel@hacettepe.edu.tr"   itemprop="  email"   data-track="  click"   data-track-action="  Email author"   data-track-label="  "  >Email author,Olgun?Güven
Affiliation:(1) Department of Chemistry, Hacettepe University, 06532 Beytepe, Ankara, Turkey
Abstract:Summary Poly (N-vinyl imidazole) (PVIm) hydrogels were prepared bygamma-irradiating binary mixtures of N-vinyl imidazole-water in a 60Co-gamma source having 4.5 kGy/h doserate. These hydrogels were characterized with gravimetric andspectrophotometric studies. Hydrogels with equilibrium swellingratio of 600% in distilled water were used in the metal ionadsorption studies. The effects of pH, equilibration time, andinitial metal ion concentration were considered in batchequilibrium study on the chelation ofCu2+,Co2+,Cd2+, andPb2+ ions. Maximum metal ionadsorption were observed at pH=6.0. It has also been observedthat the amount of adsorbed metal ions decreased at lower pHsbecause of protonation of PVIm ring.
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