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玉米基乙二醇制PET的中试研究
引用本文:周清,陈建文,吴嘉麟.玉米基乙二醇制PET的中试研究[J].合成纤维工业,2007,30(1):22-24.
作者姓名:周清  陈建文  吴嘉麟
作者单位:1. 东华大学大成集团玉米基生物材料实验室,上海,200315
2. 东华大学材料学院,上海,200051
基金项目:国家发展改革委员会重大项目
摘    要:分别将玉米基乙二醇和常规乙二醇与对苯二甲酸反应,以三氧化二锑为催化剂,添加二氧化钛和纳米二氧化硅等,制得玉米基聚酯(PET)切片和常规PET切片,经纺丝、拉伸,制得玉米基PET纤维和常规PET纤维,并对其纤维的表面形态和染色性能进行对比。结果表明:玉米基PET切片的熔点较常规PET切片的熔点低10℃,纺丝温度也低10℃;玉米基PET纤维表面粗糙,较常规PET纤维染色性能好。

关 键 词:聚对苯二甲酸乙二醇酯纤维  乙二醇  玉米  染色  色牢度
文章编号:1001-0041(2007)01-0022-03
修稿时间:2006-05-28

Pilot preparation of PET from corn-based ethylene glycol
Zhou Qing,Chen Jianwen,Wu Jialin.Pilot preparation of PET from corn-based ethylene glycol[J].China Synthetic Fiber Industry,2007,30(1):22-24.
Authors:Zhou Qing  Chen Jianwen  Wu Jialin
Affiliation:1. Corn-Based Bio-Material Engineering Lab of Dacheng.Group, Donghua University, Shanghai 200315; 2. College of Material Science and Engineering, Donghua University, Shanghai 200051
Abstract:Corn-based ethylene glycol and regular ethylene glycol were separately acted with terephthalic acid with antimony tri- oxide as a catalyst and added with titanium dioxide and nano-silicon dioxide to produce corn-based polyester(PET)and regular PET chips which were spun and drawn into corn-based PET fiber and regular PET fiber.The surface morphology and dyeing be- havior of the resulted fibers were studied and compared.The results showed that the corn-based PET chip had the melting point and the spinning temperature 10℃lower than those of the regular PET chip.The corn-based PET fiber had a rough surface and was better in dyeing behavior than the regular PET fiber.
Keywords:polyethylene terephthalate fiber  ethylene glycol  corn  dyeing  color fastness
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