| 烯烃复分解聚合用钌催化剂的合成和应用研究进展(续前) |
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| 引用本文： | 李宁,于文杰,董火成,朱小树,孙嘉鹏,王健. 烯烃复分解聚合用钌催化剂的合成和应用研究进展(续前)[J]. 化学推进剂与高分子材料, 2010, 8(5): 10-14 |
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| 作者姓名： | 李宁 于文杰 董火成 朱小树 孙嘉鹏 王健 |
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| 作者单位： | 河南科技大学,河南洛阳,471003;黎明化工研究院,河南洛阳,471000 |
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| 摘 要： | <正>(续2010年第4期第23页)3配体的影响钌金属卡宾催化剂的通式为:配体X、L、L1和R都可以根据不同的需要进行改变,配体的改变可以形成不同的钌卡宾催化剂,且会对催化剂的各项性能产生影响。科学家们长期研究发现,配体的影响具有一定的规
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| 关 键 词： | 钌催化剂 复分解 应用 合成 聚合 烯烃 金属卡宾 配体 |
Research Progress on Synthesis and Application of Ruthenium Catalyst Used in Olefin Metathesis Polymerization |
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| LI Ning,YU Wenjie,DONG Huocheng,ZHU Xiaoshu,SUN Jiapeng,WANG Jian. Research Progress on Synthesis and Application of Ruthenium Catalyst Used in Olefin Metathesis Polymerization[J]. Chemical Propellants & Polymeric Materials, 2010, 8(5): 10-14 |
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| Authors: | LI Ning YU Wenjie DONG Huocheng ZHU Xiaoshu SUN Jiapeng WANG Jian |
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| Affiliation: | 1.Henan University of Science and Technology,Luoyang 471003,China;2.Liming Research Institute of Chemical Industry,Luoyang 471000,China) |
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| Abstract: | Ruthenium carbene complex catalyst has been more and more widely applied in the olefin metathesis polymerization because of its high activity,mild reaction conditions,well tolerance to air,water and many functional groups,and attracts more attention of domestic and foreign researchers.Main synthesis methods of ruthenium carbene catalyst in recent years and the influence of different ligands on catalyst properties are summarized.The application status of ruthenium carbene catalyst in initiating dicyclopentadiene（DCPD） polymerization is described.Its development prospect and direction are also given according to domestic circumstances. |
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| Keywords: | olefin metathesis ruthenium carbene catalyst polymerization dicyclopentadiene |
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