| 超支化有机硅树脂的制备、改性及其应用 |
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| 引用本文： | 王晶,周继亮,火文君,张爱清,张道洪.超支化有机硅树脂的制备、改性及其应用[J].化工新型材料,2010,38(1). |
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| 作者姓名： | 王晶 周继亮 火文君 张爱清 张道洪 |
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| 作者单位： | 1. 中南民族大学催化材料科学国家民委-教育部共建重点实验室,武汉,430074
2. 中南民族大学催化材料科学国家民委-教育部共建重点实验室,武汉,430074;苏州海博特树脂科技有限公司,苏州,215214 |
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| 基金项目： | 中国博士后科学基金面上项目，武汉市青年科技晨光计划 |
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| 摘 要： | 综述了以ABn(n=2,3,4)型单体制备超支化聚碳硅烷、超支化聚碳硅氧烷和超支化聚烷氧基硅烷三类超支化有机硅树脂的合成工艺及其改性技术,重点介绍了制备含不饱和双键和环氧基团的功能性超支化有机硅树脂单体的分子设计与制备技术。论述了超支化有机硅树脂在薄膜材料、复合催化剂、增强助剂等领域的应用研究进展。
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| 关 键 词： | 超支化聚合物 超支化有机硅树脂 制备 |
Preparation, modification and application of hyperbranched organosilicon resins |
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| Wang Jing,Zhou Jiliang,Huo Wenjun,Zhang Aiqing,Zhang Daohong.Preparation, modification and application of hyperbranched organosilicon resins[J].New Chemical Materials,2010,38(1). |
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| Authors: | Wang Jing Zhou Jiliang Huo Wenjun Zhang Aiqing Zhang Daohong |
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| Abstract: | Synthesis and modification technology of hyperbranehed organosilicon resins from ABn(n= 2,3,4) mon-omers were summarized in detail, including hyperbranehed polycarbosilanes, hyperbranched polycarbosiloxanes and hyper-branched polyalkoxysilanes. Especially, monomer molecular designation and preparation method of funcational hyper-branched organosilicon resins containing unsaturated double-bonds and epoxy group also were diseuused. Application pro-gress of hyperbranched organosilicon resins in membrane materials, complex catalysts and reinforcement additives fields were reviewed. |
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| Keywords: | hyperbranched polymer hyperbranched organosilicon resin preparation |
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