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Liquid-rubber-modified epoxy adhesives cured with dicyandiamide. I. Preparation and characterization
Authors:Yu-Der Lee  Shi-Kwun Wang  Wei-Kuo Chin
Abstract:n-Butylacrylate/acrylic acid (nBA/AA) copolymers were synthesized and used to modify epoxy resin (DGEBA) cured with dicyandiamide (DICY). The precuring reaction between nBA/AA copolymer and DGEBA, the curing cycle of DGEBA, and the effects of DICY and aluminum powder upon the adhesive strengths of modified DGEBA were studied. It was found that the optimum DICY/DGEBA ratio was 6 g/100 g, and lap shear strength and T-peel strength increased with increasing amount of aluminum powder. The curing cycle for modified DGEBA was determined to be 1 h at 177°C.
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