Heat pump assisted distillation. III: Experimental studies using an external heat pump

An experimental study has been carried out on a continuously operated pilot fractional distillation column equipped with an external heat pump. The distillation column was a 15 cm diameter glass unit containing eleven single bubble cap plates. A methanol-water mixture was fed to the column and the heat pump working fluid was R114. The actual coefficient of performance (COP)_A of the heat pump increased with an increase in the mass flow rate of the working fluid. A maximum (COP)_A value of 4–3 was obtained with a gross temperature lift of 41–3°C. The performance of two reciprocating compressors was compared. The experiments have shown that continuous heat pump assisted distillation using an external working fluid can greatly reduce the energy used in a distillation process. No control problems were encountered in the experiments.