Diels-Alder Reaction of [60]Fullerene with Dienes Having an Ester Substituent at 1-Position |
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Authors: | Kou-Fu Liou Tsung-Yu Hsiao Chien-Hong Cheng |
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Affiliation: | a Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan, Republic of China |
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Abstract: | Treatment of [60]fullerene with ethyl trans, trans-hexa-2,4-dienoate (1) and methyl trans, trans-octa-2,4-dienoate (2) at 70 ∼ 100 °C afforded products 3 and 4, respectively, which are resulted from Diels-Alder addition of the dienoates to a 6/6 ring junction of [60]fullerene. |
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