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Diels-Alder Reaction of [60]Fullerene with Dienes Having an Ester Substituent at 1-Position
Authors:Kou-Fu Liou   Tsung-Yu Hsiao  Chien-Hong Cheng
Affiliation: a Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan, Republic of China
Abstract:Treatment of [60]fullerene with ethyl trans, trans-hexa-2,4-dienoate (1) and methyl trans, trans-octa-2,4-dienoate (2) at 70 ∼ 100 °C afforded products 3 and 4, respectively, which are resulted from Diels-Alder addition of the dienoates to a 6/6 ring junction of [60]fullerene.
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