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炼油厂高标溶剂油类别优选研究
引用本文:刘忠运,李莉娜. 炼油厂高标溶剂油类别优选研究[J]. 上海化工, 2009, 34(8): 15-17
作者姓名:刘忠运  李莉娜
作者单位:1. 长江大学油气钻采工程湖北省重点实验室,湖北荆州,434023
2. 天津理工大学化学化工学院,天津,300384
基金项目:中国海洋石油总公司资助项目 
摘    要:通过蒸馏实验对某炼油厂提供的各种石脑油的馏分范围进行测试,并用气相色谱仪对其化学组成进行详一细分析,结果表明抽余油具有制备低芳烃6号溶剂油的物质条件。实验与模拟计算表明:该抽余油经催化加氢分馏可制得芳烃〈10mg/L、d硫〈0.5mg/L的6号溶剂油;对该6号溶剂油进一步精馏则可制得纯度为99%的异己烷和纯度为98%的己烷两种高标溶剂油。与常规溶剂油及D系列溶剂油相比,正已烷价格与石脑油平均差价高达4000元/吨,且差价稳定,因此以抽余油生产正已烷/异己烷可获良好的经济效益。

关 键 词:溶剂油  脱芳烃  脱硫  窄馏分  已烷  异己烷

Research on Optimum Select of High Standard Solvent Oil Type from a Refinery
Liu Zhongyun,Li Lina. Research on Optimum Select of High Standard Solvent Oil Type from a Refinery[J]. Shanghai Chemical Industry, 2009, 34(8): 15-17
Authors:Liu Zhongyun  Li Lina
Affiliation:Liu Zhongyun Li Lina
Abstract:After testing the fraction range of various naphtha provided by a refinery by distillation experiment and detailed analyzing to the chemical substance structure of naphtha by gas chromatograph,the result shows that the raffinate oil has the material conditions producing the 6# solvent oil with low aromatic bydrocarbon.Simulation calculation shows that the raffinate oil can produce the 6# solvent oil which is aromatic hydrocarbon〈10mg/L and sulfur〈0.5mg/L by catalytic hydrogenation.The above 6# extract solvent oil can produce two high standard solvent oil by further distillation,which are hexane with the purity 98% and isohexane with the purity 99%.Compared with conventional and D series solvent oil,the difference of average prices between hexane and naphtha is up to 4000yuan/t and the difference is stable,so it is available to produce isohexane and bexane using raffinste oil to gain good economic benefits.
Keywords:Solvent oil  Dearomatization  Desulfidation  Close-cut fraction  Hexane  Isohexane
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