Some barium titanate based dielectrics |
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Authors: | A M Varaprasad D K Chakrabarty A B Biswas |
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Affiliation: | (1) Solid State Laboratory, Chemistry Department, Indian Institute of Technology, 400 076 Bombay, India;(2) Present address: Hindustan Lever Research Centre, 400 093 Bombay, India |
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Abstract: | Some new potential dielectric materials have been made through the cross-substitution of Ba2+ by a 1:1 molar combinations of tri-(La3+) and mono-valent (Li+, Na+, K+) ions at the Ba2+ site in BaTiO3. Chemical analysis shows that compositions in the potassium series are about 6·1% deficient in their K2O content and exhibit interesting dielectric relaxations. The cross-substitution has lowered theT c down to room temperature. The disorder in the larger ‘A’ cation sublattice of the three systems has been established by infra-red and x-ray data. This leads to microscopic compositional variations, which in turn can account for the diffuseness of the dielectric anomalies observed in the barium titanate-rich compositions (0⩽x⩽0·3). since deceased. |
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Keywords: | Dielectrics ceramics phase transformation barium titanate |
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