Synthesis, characterization and hydroisomerization catalytic performance of nanosize SAPO-11 molecular sieves |
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Authors: | Shengzhen Zhang Sheng-Li Chen Peng Dong Zhiyong Ji Junying Zhao Keqi Xu |
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Affiliation: | (1) State Key Laboratory of Heavy Oil Processing, College of Chemistry and Chemical Engineering, China University of Petroleum, Beijing, 102249, P. R. China |
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Abstract: | A new static hydrothermal method was developed for synthesizing nanosize SAPO-11 molecular sieve.The new method involves aging
pretreatment step followed by crystallization process of a precursor gel. The effect of the aging pretreatment on morphology
and size of SAPO-11 molecular sieves was investigated. The results of XRD and SEM showed that the aging pretreatment changed
the size and morphology of the SAPO-11 dramatically, and the size could be controlled by varying the time for aging. Nanocrystals
of SAPO-11 molecular sieves were synthesized by aging the precursor gel at 150 °C for 135 min and then crystallizing the gel
at 190 °C for 24 h. Compared with the SAPO-11 samples that exhibit the pseudo-spherical aggregates ranging from 3 to 15 μm
synthesized by conventional method, the SAPO-11 samples synthesized by the new method not only possessed much smaller cubic
single crystals of about 400–500 nm, but were more uniform in size. Moreover, the SAPO-11 samples synthesized by the new method
had larger specific surface area and larger external specific surface area. The results of n−hexadecane hydroisomerization showed that the Pt/SAPO-11 prepared with the new method exhibited higher catalytic activity
and better hydroisomerization selectivity than the Pt/SAPO-11 synthesized by conventional hydrothermal method. |
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Keywords: | aging treatment hydroisomerization nanocrystals n− hexadecane SAPO-11 molecular sieves static hydrothermal synthesis |
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